Investigation of growth, optical properties, polarizability, and photoluminescence behaviour of the NLO single crystal of 1-Carboxy-2-Methylpropan-1-Aminium Chloride 2-Azaniumyl-3-methylbutanoate for Photonic Applications

  • Unique Paper ID: 196953
  • Volume: 12
  • Issue: 11
  • PageNo: 4249-4254
  • Abstract:
  • The slow evaporation solution growth method was used to synthesise a nonlinear optical single crystal of 1-Carboxy-2-Methylpropan-1-Aminium Chloride 2-Azaniumyl-3-methylbutanoate using ethanol as solvent. The crystallisation process yielded a well-defined monoclinic system with centrosymmetric nature of P21 space group crystal, was revealed by comprehensive of single crystal X-ray diffraction analysis. UV-Vis-NIR spectroscopy, revealing a significant cut-off wavelength of the title compound. Urbach energy, which measures the width of the bandgap tails in semiconductors, showed a low value, indicating that grown crystal has excellent crystallinity, as well as a steepness parameter indicating sharp absorption edges. The electron-phonon interaction energy was estimated, offering insights into the coupling between electronic states and lattice vibrations. The grown material optical constants graphs such as the optical conductivity, extinction coefficient and refractive index were plotted with the function of optical absorption, wavelength and photon energy for assessing optical applications. Photoluminescence analysis demonstrated the excellent structural quality of the grown crystal. The grown compound electronic polarizability was estimated quantitatively, further advancing the understanding of its electro-optic properties. These comprehensive findings suggest that the compound has strong potential for use in nonlinear optical (NLO) devices.

Copyright & License

Copyright © 2026 Authors retain the copyright of this article. This article is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

BibTeX

@article{196953,
        author = {Dr.N.Mahalakshmi and M Parthasarathy},
        title = {Investigation of growth, optical properties, polarizability, and photoluminescence behaviour of the NLO single crystal of 1-Carboxy-2-Methylpropan-1-Aminium Chloride 2-Azaniumyl-3-methylbutanoate for Photonic Applications},
        journal = {International Journal of Innovative Research in Technology},
        year = {2026},
        volume = {12},
        number = {11},
        pages = {4249-4254},
        issn = {2349-6002},
        url = {https://ijirt.org/article?manuscript=196953},
        abstract = {The slow evaporation solution growth method was used to synthesise a nonlinear optical single crystal of 1-Carboxy-2-Methylpropan-1-Aminium Chloride 2-Azaniumyl-3-methylbutanoate using ethanol as solvent. The crystallisation process yielded a well-defined monoclinic system with centrosymmetric nature of P21 space group crystal, was revealed by comprehensive of single crystal X-ray diffraction analysis. UV-Vis-NIR spectroscopy, revealing a significant cut-off wavelength of the title compound. Urbach energy, which measures the width of the bandgap tails in semiconductors, showed a low value, indicating that grown crystal has excellent crystallinity, as well as a steepness parameter indicating sharp absorption edges. The electron-phonon interaction energy was estimated, offering insights into the coupling between electronic states and lattice vibrations. The grown material optical constants graphs such as the optical conductivity, extinction coefficient and refractive index were plotted with the function of optical absorption, wavelength and photon energy for assessing optical applications. Photoluminescence analysis demonstrated the excellent structural quality of the grown crystal. The grown compound electronic polarizability was estimated quantitatively, further advancing the understanding of its electro-optic properties. These comprehensive findings suggest that the compound has strong potential for use in nonlinear optical (NLO) devices.},
        keywords = {Structural refinement, Refractive index, Optical conductivity, electronic polarizability, Photoluminescence.},
        month = {April},
        }

Cite This Article

Dr.N.Mahalakshmi, , & Parthasarathy, M. (2026). Investigation of growth, optical properties, polarizability, and photoluminescence behaviour of the NLO single crystal of 1-Carboxy-2-Methylpropan-1-Aminium Chloride 2-Azaniumyl-3-methylbutanoate for Photonic Applications. International Journal of Innovative Research in Technology (IJIRT), 12(11), 4249–4254.

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