Ultrasonic and Thermodynamic Investigations of Concentrated Aqueous Solutions of RbCl and CsCl
Author(s):
Prakash Chandra, Rakesh Kumar Singh, Chandrabhan Singh Niranjan, Rekha Lagarkha
Keywords:
Apparent molar volume, adiabatic compressibility, hydration number, ion-solvent interaction.
Abstract
This study presents a comprehensive analysis of concentrated aqueous solutions of Rubidium Chloride (RbCl) and Cesium Chloride (CsCl) using ultrasonic and thermodynamic techniques. The behavior of these solutions under varying concentrations and temperatures provides valuable insights into their structural and thermodynamic properties. Ion-solvent interactions of electrolyte play very significant role in understanding the nature, physicochemical behaviour and forces operating between the component molecules in the solutions. In the present study most widely investigated thermodynamic properties of electrolyte solutions include the density (T,c), the expansion coefficient(T,c), the apparent molar volumes V(T,c) and limiting apparent molar volume constant Sv, adiabatic compressibility , hydration number , apparent molar compressibility , limiting apparent molar compressibility , and constant SK. These properties provide better insight into the ionic interactions in solution of electrolytes. The findings of this research contribute to the fundamental understanding of the properties of concentrated aqueous solutions of RbCl and CsCl, which have implications in various fields including chemical engineering, pharmaceuticals, and environmental science. Additionally, the data obtained can serve as a reference for further theoretical modeling and experimental studies in similar systems.
Article Details
Unique Paper ID: 162400

Publication Volume & Issue: Volume 10, Issue 10

Page(s): 54 - 61
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