SYNTHESIS, CHARACTERIZATION AND ELECTROCHEMICAL PROPERTIES OF Ru (II, III) COMPLEXES DERIVE FROM POLYFUNCTIONAL DISALICYLALDEHYDE MALONOYLDIHYDRAZONE

  • Unique Paper ID: 182349
  • Volume: 7
  • Issue: 10
  • PageNo: 766-775
  • Abstract:
  • Ruthenium (II and III) complexes have been synthesized from reaction of RuCl3.3H2O with salicylaldehydemalonoyldihydrazone (slmhH4) in methanol medium under various experimental conditions. The composition of the complexes has been established from the data obtained from elemental analyses, thermo analysis and FAB mass spectra. The structural assessment of the complexes has been carried out based on data obtained from molar conductivity, magnetic susceptibility, electronic, IR and ESR, Electron transfer properties of the monometallic complexes have been studied using cyclic voltammetry technique.

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