ELECTRICAL AND DIELECTRICAL STUDIES ON Na+ ION BASED NANO ALUMINA(Al2O3) DISPERSED SOLID POLYMER ELECTROLYTE SYSTEM

  • Unique Paper ID: 169038
  • PageNo: 923-929
  • Abstract:
  • Sodium-ion based PEO-80:NaPF6-10:Al2O3-10 dispersed solid electrolyte system was synthesized through solution casting method is presented in this paper. Structural, morphological and thermal properties have been carried out by using techniques like XRD, SEM, FTIR, DSC and Impedance Spectroscopy is employed to study the electrical and dielectrical behavior of the system. FTIR studies have confirmed the presence of various vibrational modes and the interactions among molecules of polymer, salt, and nano-dispersoid. The DSC investigations indicate the melting points of pure and dispersed systems and revealed the absence of any phase transition in all the three systems. X- Ray diffactograms provide the crystalline nature of pure PEO, NaPF6, Al2O3, and PEO-NaPF6-Al2O3 system. SEM micrographs visualize the surface morphology of the mixed system and the distribution of Al2O3 within the polymer matrix. Impedance analyses is carried out to evaluate the dc ionic conductivity and activation energy. The variation of real and imaginary components of ac conductivity, dielectric constant, dielectric loss and electric modulus with temperature and frequency show the existence of various types of polarizations at low frequencies disappear at high frequency region and enhanced dc conductivity is attributed to the increased concentration of charge carriers in the dispersed system and increased hopping frequency of mobile charge carriers could be responsible for higher ac conductivity at higher frequencies.

Copyright & License

Copyright © 2026 Authors retain the copyright of this article. This article is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

BibTeX

@article{169038,
        author = {MOTHKURI  MANASA and R Swarna Latha and Venkatraramana Jeedi and S Narender Reddy},
        title = {ELECTRICAL AND DIELECTRICAL STUDIES ON Na+ ION   BASED NANO ALUMINA(Al2O3) DISPERSED SOLID POLYMER ELECTROLYTE SYSTEM},
        journal = {International Journal of Innovative Research in Technology},
        year = {2024},
        volume = {11},
        number = {6},
        pages = {923-929},
        issn = {2349-6002},
        url = {https://ijirt.org/article?manuscript=169038},
        abstract = {Sodium-ion based PEO-80:NaPF6-10:Al2O3-10 dispersed solid electrolyte system was synthesized through solution casting method is presented in this paper. Structural, morphological and thermal properties have been carried out by using techniques like XRD, SEM, FTIR, DSC and Impedance Spectroscopy is employed to study the electrical and dielectrical behavior of the system.  FTIR studies have confirmed the presence of various vibrational modes and the interactions among molecules of  polymer, salt, and nano-dispersoid. The DSC investigations indicate the melting points of pure and dispersed systems and revealed the absence of any phase transition in all the three systems. X- Ray diffactograms provide the crystalline nature of  pure PEO, NaPF6, Al2O3, and PEO-NaPF6-Al2O3 system. SEM  micrographs visualize the surface morphology of the mixed system and the distribution of  Al2O3 within the polymer matrix. Impedance analyses is carried out to evaluate the dc ionic conductivity and activation energy. The variation of  real and imaginary components of ac conductivity, dielectric constant, dielectric loss and electric modulus with temperature  and  frequency show the existence of various types of polarizations at low frequencies disappear at high frequency region and enhanced dc conductivity is attributed to the increased concentration of charge carriers in the dispersed system  and increased hopping frequency of mobile charge carriers  could be responsible for higher ac conductivity at higher frequencies.},
        keywords = {Polymer Electrolyte, Al2O3, XRD, FTIR, SEM, DSC, Impedance spectroscopy.},
        month = {November},
        }

Cite This Article

MANASA, M. ., & Latha, R. S., & Jeedi, V., & Reddy, S. N. (2024). ELECTRICAL AND DIELECTRICAL STUDIES ON Na+ ION BASED NANO ALUMINA(Al2O3) DISPERSED SOLID POLYMER ELECTROLYTE SYSTEM. International Journal of Innovative Research in Technology (IJIRT), 11(6), 923–929.

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