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@article{182321,
author = {Kriti kumari and Dr. Hari Om Pandey},
title = {Microwave assisted Synthesis and study of some chromium (III) complexes of L- Arabinose with TBC in Distilled water},
journal = {International Journal of Innovative Research in Technology},
year = {2025},
volume = {12},
number = {2},
pages = {1414-1418},
issn = {2349-6002},
url = {https://ijirt.org/article?manuscript=182321},
abstract = {This study reports the microwave-assisted synthesis and characterization of chromium (III) complexes derived from L-arabinose using tertiary butyl chromate (TBC) as the chromium source in distilled water as the reaction medium. The synthesis was performed under controlled conditions with varying molar ratios of L-arabinose to TBC (1:3, 1:2, 1:1, 2:1, and 3:1) to evaluate the influence of stoichiometry on complex formation and stability. Microwave irradiation was employed to enhance reaction kinetics, resulting in shorter reaction times and improved yields compared to conventional methods. The resulting complexes were characterized using UV-Visible spectroscopy, Fourier-transform infrared (FTIR) spectroscopy, magnetic susceptibility, and molar conductivity measurements. FTIR analysis indicated coordination through hydroxyl groups of L-arabinose, suggesting chelation with the chromium center. Spectral data supported the formation of octahedral Cr (III) complexes. The variation in molar ratios demonstrated notable effects on the coordination environment and the stability of the complexes. These findings highlight the efficiency of microwave-assisted synthesis in preparing chromium (III) carbohydrate complexes and provide insight into the coordination behaviour of L-arabinose with chromium-based oxidants in aqueous media.},
keywords = {L-Arabinose, Tertiary butyl chromate (TBC), Distilled Water (DW), FTIR, TGA-DTA.},
month = {July},
}
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