Thermal decomposition kinetics of Zn(II), Cd(II) and Pd(II) chelates of 5,5-dimethyl1,3-cyclohexanedionebis(thisemicarbazone)

  • Unique Paper ID: 154018
  • Volume: 8
  • Issue: 9
  • PageNo: 435-438
  • Abstract:
  • The Zn (II), Cd(II), and Pd (II) complexes were prepared from 5,5dimethyl1,3-cyclohexanedione bis (thiosemicarbazone) and subjected to heating at a rate of 200C per minute. The order of the reaction, mechanism, and kinetic parameters are studied using nine mechanistic and three nonmechanistic equations. The values of E, A, and ∆S were compared to choose the correct mechanism of decomposition.

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BibTeX

@article{154018,
        author = {Dr.Lali Thomas Kotturan},
        title = {Thermal decomposition kinetics of Zn(II), Cd(II) and Pd(II) chelates of 5,5-dimethyl1,3-cyclohexanedionebis(thisemicarbazone)},
        journal = {International Journal of Innovative Research in Technology},
        year = {},
        volume = {8},
        number = {9},
        pages = {435-438},
        issn = {2349-6002},
        url = {https://ijirt.org/article?manuscript=154018},
        abstract = {The Zn (II), Cd(II), and Pd (II) complexes were prepared from 5,5dimethyl1,3-cyclohexanedione bis (thiosemicarbazone) and subjected to heating at a rate of 200C per minute. The order of the reaction, mechanism, and kinetic parameters are studied using nine mechanistic and three nonmechanistic equations. The values of E, A, and ∆S were compared to choose the correct mechanism of decomposition.},
        keywords = {[Zn(5,5DMe1,3CHDTSC], [Cd(5,5DMe1,3CHDTSC)],[Pd(5,5Dme1,3CHDTSC)] 5,5-dimethyl1,3-cyclohexanedionebis(thiosemicarbazone), Dimedonebis(thiosemicarbazone)},
        month = {},
        }

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