Evaluating the Second Virial Coefficients and Thermal Conductivity of Polar Fluids: A Computational Study Using Canonical Ensemble Techniques

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Dr.Rajesh Kumar; Dr. Rajendra Kumar

Evaluating the Second Virial Coefficients and Thermal Conductivity of Polar Fluids: A Computational Study Using Canonical Ensemble Techniques

Authors: Dr.Rajesh Kumar, Dr. Rajendra Kumar

Unique Paper ID: 167723
Volume: 11
Issue: 4
PageNo: 332-336

Keywords: Canonical Average Effective Potential Lennard-Jones Potential Rowlinson Potential Second Virial Coefficients Thermal Conductivity Collision Integral.

Abstract:
Understanding the thermophysical properties of polar fluids is essential for various scientific and industrial applications. This study presents a computational analysis of the second virial coefficients and thermal conductivity of polar fluids using canonical ensemble techniques. By taking the canonical average of the Rowlinson potential and introducing it into the forces parameters of the Leonard-Jones potential, it is a useful suitable effective potential that is temperature dependant. The temperature-dependent parameters that we derive are utilized to compute the effective potential at various temperatures. We created a temperature-independent graph using the Lennard-Jones potential. The experimental and canonical effective potential values of water vapour at various temperatures. There is an excellent match between the experimental value of water vapour and the temperature-dependent CAP value of the second virial coefficients and thermal conductivity.

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Cite This Article

ISSN: 2349-6002
Volume: 11
Issue: 4
PageNo: 332-336

Evaluating the Second Virial Coefficients and Thermal Conductivity of Polar Fluids: A Computational Study Using Canonical Ensemble Techniques

Available:https://ijirt.org/article?manuscript=167723

Impact Factor
8.01 (Year 2024)

UGC Approved
Journal no 47859

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