Overcoming the Shockley-Queisser Limit: Novel Approaches in Multi-Junction and Hot-Carrier Solar Cells

  • Unique Paper ID: 189379
  • Volume: 12
  • Issue: 7
  • PageNo: 7916-7918
  • Abstract:
  • The Shockley-Queisser (SQ) limit imposes a theoretical maximum efficiency of approximately 33.7% on conventional single-junction solar cells, primarily due to transmission and thermalization losses. To meet global renewable energy targets, photovoltaic (PV) technologies must transcend this thermodynamic barrier. This article presents a comparative analysis of two leading strategies: Multi-Junction Solar Cells (MJSCs), which spatially partition the solar spectrum, and Hot-Carrier Solar Cells (HCSCs), which attempt to harvest excess kinetic energy before thermal relaxation. We review recent milestones, including the 34.85% efficiency record for perovskite-silicon tandems and the breakthrough 27.3% efficiency achieved by a perovskite hot-carrier device in 2024. The analysis highlights that while MJSCs are entering commercial maturity with established techno-economic viability, HCSCs have recently graduated from theoretical concepts to high-efficiency prototypes, offering a complementary pathway to ultra-high efficiency.

Copyright & License

Copyright © 2026 Authors retain the copyright of this article. This article is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

BibTeX

@article{189379,
        author = {Dr. Anita Sagar},
        title = {Overcoming the Shockley-Queisser Limit: Novel Approaches in Multi-Junction and Hot-Carrier Solar Cells},
        journal = {International Journal of Innovative Research in Technology},
        year = {2025},
        volume = {12},
        number = {7},
        pages = {7916-7918},
        issn = {2349-6002},
        url = {https://ijirt.org/article?manuscript=189379},
        abstract = {The Shockley-Queisser (SQ) limit imposes a theoretical maximum efficiency of approximately 33.7% on conventional single-junction solar cells, primarily due to transmission and thermalization losses. To meet global renewable energy targets, photovoltaic (PV) technologies must transcend this thermodynamic barrier. This article presents a comparative analysis of two leading strategies: Multi-Junction Solar Cells (MJSCs), which spatially partition the solar spectrum, and Hot-Carrier Solar Cells (HCSCs), which attempt to harvest excess kinetic energy before thermal relaxation. We review recent milestones, including the 34.85% efficiency record for perovskite-silicon tandems and the breakthrough 27.3% efficiency achieved by a perovskite hot-carrier device in 2024. The analysis highlights that while MJSCs are entering commercial maturity with established techno-economic viability, HCSCs have recently graduated from theoretical concepts to high-efficiency prototypes, offering a complementary pathway to ultra-high efficiency.},
        keywords = {Shockley-Queisser (SQ) limit, Multi-Junction Solar Cells, Hot-Carrier Solar Cells, ultra-high efficiency, commercial maturity},
        month = {December},
        }

Cite This Article

Sagar, D. A. (2025). Overcoming the Shockley-Queisser Limit: Novel Approaches in Multi-Junction and Hot-Carrier Solar Cells. International Journal of Innovative Research in Technology (IJIRT), 12(7), 7916–7918.

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