Thermal decomposition kinetics of Zn(II), Cd(II) and Pd(II) chelates of 5,5-dimethyl1,3-cyclohexanedionebis(thisemicarbazone)

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ISSN: 2349-6002 ESTD Year: 2014

UGC approved journal no 47859

Thermal decomposition kinetics of Zn(II), Cd(II) and Pd(II) chelates of 5,5-dimethyl1,3-cyclohexanedionebis(thisemicarbazone)
Author(s):
Dr.Lali Thomas Kotturan
Keywords:
[Zn(5,5DMe1,3CHDTSC], [Cd(5,5DMe1,3CHDTSC)],[Pd(5,5Dme1,3CHDTSC)] 5,5-dimethyl1,3-cyclohexanedionebis(thiosemicarbazone), Dimedonebis(thiosemicarbazone)
Abstract
The Zn (II), Cd(II), and Pd (II) complexes were prepared from 5,5dimethyl1,3-cyclohexanedione bis (thiosemicarbazone) and subjected to heating at a rate of 200C per minute. The order of the reaction, mechanism, and kinetic parameters are studied using nine mechanistic and three nonmechanistic equations. The values of E, A, and ∆S were compared to choose the correct mechanism of decomposition.
Article Details
Unique Paper ID: 154018 Publication Volume & Issue: Volume 8, Issue 9 Page(s): 435 - 438
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