STUDY OF MICELLAR CATALYSED OXIDATION OF SACCHARIDES BY N-BROMOSUCCINIMIDE

  • Unique Paper ID: 191707
  • Volume: 12
  • Issue: 8
  • PageNo: 8949-8953
  • Abstract:
  • Micellar catalyzed oxidation of certain monosaccharides in aqueous acetic acid medium were discussed with an emphasis of correlation of structure and reactivity. The reaction obeyed first-order kinetics in [NBS], and less than unit order in [H+]. The reaction was observed to proceed through formation of 1:1 intermediate complex between HOBr, and H2O+ Br reacting species of oxidant, and substrate. The reaction is initially catalyzed by micellar CTAB at optimum concentration. Two mechanisms-one pathway is independent [H+], and the other on dependent [H+], with involvement of water molecule in slow step are discussed. The derived rate law was verified graphically in consistent with the experimental results.

Copyright & License

Copyright © 2026 Authors retain the copyright of this article. This article is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

BibTeX

@article{191707,
        author = {Gorelal Vishwakarma and K.N. Sharma},
        title = {STUDY OF MICELLAR CATALYSED OXIDATION OF SACCHARIDES BY N-BROMOSUCCINIMIDE},
        journal = {International Journal of Innovative Research in Technology},
        year = {2026},
        volume = {12},
        number = {8},
        pages = {8949-8953},
        issn = {2349-6002},
        url = {https://ijirt.org/article?manuscript=191707},
        abstract = {Micellar catalyzed oxidation of certain monosaccharides in aqueous acetic acid medium were discussed with an emphasis of correlation of structure and reactivity. The reaction obeyed first-order kinetics in [NBS], and less than unit order in [H+]. The reaction was observed to proceed through formation of 1:1 intermediate complex between HOBr, and H2O+ Br reacting species of oxidant, and substrate. The reaction is initially catalyzed by micellar CTAB at optimum concentration. Two mechanisms-one pathway is independent [H+], and the other on dependent [H+], with involvement of water molecule in slow step are discussed. The derived rate law was verified graphically in consistent with the experimental results.},
        keywords = {L-arabinose, D-glucose, N-Bromo succinimide, Micellar, oxidation.},
        month = {January},
        }

Cite This Article

Vishwakarma, G., & Sharma, K. (2026). STUDY OF MICELLAR CATALYSED OXIDATION OF SACCHARIDES BY N-BROMOSUCCINIMIDE. International Journal of Innovative Research in Technology (IJIRT), 12(8), 8949–8953.

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